Research & Development
ZHANG Zhao, LI Jipeng, QIAO Degao, YANG Hua, LIU Jingyu, ZHENG Guosheng, CAO Guangming
To solve the problem of thick oxide scale and color variation between edges and center of S355GD-M strip, in-situ observations were conducted on oxide scale formation during the heating, and experimental studies were performed on the structural transformation of surface oxide scale after strip cooling at different coiling temperatures. Results indicate that oxide scale on S355GD-M slab surfaces during heating progresses through several stages: intergranular growth, dense growth, loose growth, aggregated longitudinal growth, and stable growth. At the beginning of oxidation, the specimen surface is not covered by oxidation products, allowing Fe atoms in the substrate to fully contact O2. Due to higher energy at grain boundaries within the substrate, oxidation products nucleate preferentially at grain boundaries. As temperature further increases, grain boundaries become fully covered by oxidation products, and the oxidation reaction proceeds toward non-grain boundary regions until the specimen surface is completely covered by dense oxidation products. At this time, the outermost layer of oxidation products in contact with O2 exhibits the highest oxygen concentration, where FeO is oxidized to Fe2O3 and Fe3O4 and begins longitudinal growth. As the coiling temperature decreases, the proportion of eutectoid structure first increases and then gradually decreases. Conversely, as the cooling rate decreases, the proportion of eutectoid structure gradually increases. Based on experimental results, a CCT curve for the FeO structural transformation within the iron oxide scale was plotted, revealing compliance with the C-curve pattern, with a nose temperature around 500 ℃. Based on in-situ observation results, higher temperatures accelerate iron oxide scale growth. An effective strategy to reduce iron oxide scale thickness is to minimize the strip's prolonged exposure to high temperatures. By lowering the starting rolling temperature, increasing the finishing rolling temperature, and raising the strip rolling speed, the high-temperature dwell time was effectively reduced, achieving the goal of thinning the oxide scale. The structural differences in oxide scale primarily result from varying cooling rates across different strip locations. Based on experimental results of FeO eutectic phase transformation, the coiling system was adjusted by setting the coiling temperature near the nose tip temperature, thereby reducing structural variations between the strip edges and center. Following process optimization, the thickness of the oxide scale on the surface of S355GD-M strip reached about 12 μm. Both the edge and center regions exhibited an oxide scale structure composed of Fe3O4 + FeO + eutectic phase. This significantly improved surface color defects, enhancing the surface quality of the hot-rolled product.